Regiospecific and stereoselective carbometallation of alkynylsilanes by Ziegler-Natta alkylating agents

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

David E. Van Horn, Ei‐ichi Negishi · Journal of the American Chemical Society · 1978 · 284 citations

Natural Sciences, Chemistry, Catalysis +16

New synthesis of aldehydes via vinylsilanes

Gilbert Stork, Ernest W. Colvin · Journal of the American Chemical Society · 1971 · 128 citations

Natural Sciences, Chemistry, Analytical Chemistry +5

Polymerization of Ethylene with Bis-(cyclopentadienyl)-titanium Dichloride and Diethylaluminum Chloride

Wendell P. Long, David S. Breslow · Journal of the American Chemical Society · 1960 · 127 citations

Natural Sciences, Chemistry, Analytical Chemistry +7

The Active Species in Homogeneous Ziegler‐Natta Catalysts for the Polymerization of Ethylene

G. Henrici‐Olivé, S. Olivé · Angewandte Chemie International Edition in English · 1967 · 103 citations

Natural Sciences, Chemical Engineering, Chemistry +15

Organometallic compounds of Group III. XXXV. The stereospecific reductive alkylation of acetylenes by successive hydralumination and carbodemetalation

John J. Eisch, George A. Damasevitz · The Journal of Organic Chemistry · 1976 · 86 citations

Natural Sciences, Chemistry, Catalysis +8