Fabrication of Designed Architectures of Au Nanoparticles on Solid Substrate with Printed Self-Assembled Monolayers as Templates

Abstract

This paper provides a convenient method for fabricating architectures of Au nanoparticles on solid substrate,with precise position and density control. Our strategy is to modify Au substrate with self-assembled monolayers (SAMs) terminated with different functional groups. They were chosen to be −CH 3 /−NH 2 or −CH 3 /−SH according to their affinities to Au nanoparticle. Au nanoparticles assemble selectively on −NH 2 or −SH terminated locations, the −NH 2 functional group binding electrostatically to the nanoparticles whereas the −SH groups bonding chemically. The SAMs, acting as guiding templates for Au nanoparticles, were fabricated by the microcontact printing (μCP) technique. A patterned or unpatterned SAM was prepared by using patterned or unpatterned poly(dimethyl)siloxane (PDMS) stamp, respectively. The coverage of −CH 3 terminated SAM in the contact region is controlled by changing the concentration of “ink” solution for the stamp. After immersing the printed SAM into −SH or −NH 2 thiol solutions for 2 h, a mixed SAM with a predetermined coverage of −SH or −NH 2 was formed in the contact regions, and a pure −SH or −NH 2 SAM was formed in the intervening area. The position and density of nanoparticles on the surface were determined by the distribution of the underlying functional groups.