Canadian Journal of Chemistry · 1963 · 121 citations · 21 references
Natural SciencesChemistryChemical KineticsOrganic ChemistryOxidation ReactionsRadical ReactionsSubstituent EffectsAutoxidation ChemistryElectrophilic ReactivityHydrogen Abstraction ReactionsPhenolic Compound ReactivitySubstituent Constants
The relative rates of reaction of 11 meta- and para-substituted phenols with styrylperoxy radicals have been measured at 65 °C and have been shown to give an excellent correlation with electrophilic substituent constants. The reaction is compared with a number of similar hydrogen abstraction reactions.
21
Charles E. Boozer, George S. Hammond, Chester E. Hamilton et al. · Journal of the American Chemical Society · 1955 · 200 citations