Sulfur Dioxide Insertion Reactions of some Compounds containing Sn—C and Fe—Sn—C Bonds

Abstract

The preparations of [CpFe(CO) 2 ] 2 Sn[OS(O)Ph] 2 , CpFe(CO) 2 SnPh[OS(O)Ph] 2 , CpFe(CO) 2 SnPh[OS(O)Ph]OH, and Ph 2 Sn[OS(O)Ph] 2 by sulfur dioxide insertion into the C—Sn bond and also by reaction of the sodium phenyl sulfinate with the corresponding chloro-compounds are reported. The infrared (i.r.) spectra and some reactions of these compounds are also discussed.