Bromide Adsorption on Ag(001): A Potential Induced Two-Dimensional Ising Order-Disorder Transition

Abstract

The adsorption of bromide on an Ag(001) electrode has been investigated using in situ x-ray scattering methods. With increasing potential, the bromide undergoes a second order phase transition from a lattice gas to an ordered $c(2\ifmmode\times\else\texttimes\fi{}2)$ structure. The order parameter is consistent with the 2D Ising model prediction $\ensuremath{\beta}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}1/8$. A comparison of x-ray and electrochemical measurements indicates significant lateral disorder at low coverages which decreases with increasing coverage.