Concepedia

Design and Synthesis of Novel Propellanes by Using Claisen Rearrangement and Ring‐Closing Metathesis as the Key Steps

Sambasivarao Kotha, Mirtunjay Kumar Dipak

Chemistry - A European Journal · 2006 · 60 citations · 20 references

DOI

Concepts

Abstract

Novel hexacyclic caged compounds are prepared by a combination of Claisen rearrangement and ring-closing metathesis (RCM). Additionally, a Grignard reaction in conjugation with RCM produced intricate hexacyclic caged molecules.

References

20

Synthesis and Activity of a New Generation of Ruthenium-Based Olefin Metathesis Catalysts Coordinated with 1,3-Dimesityl-4,5-dihydroimidazol-2-ylidene Ligands

Matthias Scholl, Sheng Ding, Choon Woo Lee et al. · Organic Letters · 1999 · 3.4K citations

, , +15

A Series of Well‐Defined Metathesis Catalysts–Synthesis of [RuCl<sub>2</sub>(CHR′)(PR<sub>3</sub>)<sub>2</sub>] and Its Reactions

Peter Schwab, Marcia B. France, Joseph W. Ziller et al. · Angewandte Chemie International Edition in English · 1995 · 1.5K citations

, , +16

Olefin metathesis

Robert H. Grubbs · Tetrahedron · 2004 · 1.2K citations

Reactions of Ruthenium Carbenes of the Type (PPh3)2(X)2Ru:CH-CH:CPh2 (X = Cl and CF3COO) with Strained Acyclic Olefins and Functionalized Olefins

Zhe Wu, SonBinh T. Nguyen, Robert H. Grubbs et al. · Journal of the American Chemical Society · 1995 · 216 citations

, , +5

A novel, versatile synthetic approach to linearly fused tricyclopentanoids via photo-thermal olefin metathesis

Goverdhan Mehta, A. Srikrishna, Ambati V. Raghava Reddy et al. · Tetrahedron · 1981 · 146 citations

, , +14