Strahlenchemische Reduktion aromatischer Nitroverbindungen mit Fe(CO)₅

Abstract

Mixtures of aromatic nitro compounds and Fe (CO) 5 are reduced by the action of light or 60 Co-γ to the corresponding nitroso compounds, which simultaneously form monomeric or dimeric irontricarbonyl complexes. The influence of substituents on the structure of these complexes is discussed on the basis of IR and UV data.