Concepedia

A 4+3 Cycloaddition Approach to the Synthesis of (±)-Sterpurene

Michael Harmata, Gary Bohnert

Organic Letters · 2002 · 56 citations · 31 references

DOI

Concepts

Abstract

A synthesis of the sesquiterpene sterpurene is presented. Key steps include a 4+3 cycloaddition reaction and a quasi-Favorskii rearrangement. [reaction--see text]

References

31

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, , +6

An enantioselective central-axial-central chiral element transfer process leading to a concise synthesis of (+)-sterpurene: intramolecular Diels-Alder reactions of vinylallene sulfoxides

Richard A. Gibbs, Karin Bartels, Robert W. K. Lee et al. · Journal of the American Chemical Society · 1989 · 91 citations

, , +6

A short enantioselective synthesis of (+)-sterpurene: complete intramolecular transfer of central to axial to central chiral elements

Richard A. Gibbs, William H. Okamura · Journal of the American Chemical Society · 1988 · 81 citations

, , +6

Stereoselective electroreductive cyclization pathway to the isolactarane-type sesquiterpene 1-sterpurene

Luc Moëns, Manuel M. Baizer, R. Daniel Little · The Journal of Organic Chemistry · 1986 · 74 citations

, , +7

Synthesis of All Eight Stereoisomers of the Germination Stimulant Strigol

Anat Reizelman, Marc Scheren, G. H. L. Nefkens et al. · Synthesis · 2000 · 58 citations

, , +10