Photochromism of doped terbium gallium garnet

Abstract

In order to understand the photochromic effect in terbium gallium garnet doubly doped with calcium and cerium, the spectral characteristics of absorption changes induced by heating and irradiation are studied. Based on the findings we conclude that the photochromic band at $420\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$ originates from defects involving ${\mathrm{Tb}}^{4+}$. Previously the band was attributed to ${\mathrm{Ce}}^{3+}$. Two possible models are suggested and discussed, both of which are in agreement with the obtained experimental results.