Two-dimensional nuclear magnetic resonance correlation spectroscopy at zero field

Abstract

Three methods for two-dimensional correlation nuclear magnetic resonance spectroscopy at zero field are discussed. All three involve coherence transfer via longitudinal polarization, double quantum coherence, or both in parallel. The double quantum pulse sequences exploit the spinor property of spin states. These sequences have been applied to connected Δm=1 transitions, as well as for the indirect detection of forbidden or nearly forbidden Δm>1 transitions.