The Journal of Chemical Physics · 1970 · 30 citations · 13 references
Natural SciencesChemistryPhysicsAnalytical ChemistryMass Spectrometric AnalysisSpectroscopyMass SpectrometryOxidation-reduction ReactionsCollision Cross SectionsFragmentation PathwaysReaction Mechanism DerivationReaction Mechanism ElucidationTandem Mass Spectrometry
The reaction of C+(2P) with CH4 has been investigated in the 2–200-eV energy region using a tandem mass spectrometer. All possible ions containing one or two carbon atoms were observed except C2H4+. The behavior of the cross sections as a function of the kinetic energy of the incident ion was used to infer reaction mechanism. Evidence was obtained for the presence of a complex, stripping and binary collision mechanisms.
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