Studies on the transition metal-catalyzed synthesis of variously substituted (E)-3-[1-(aryl)methylidene]- and (E)-3-(1-alkylidene)-3H-furan-2-ones

A convenient synthesis of acetylenes: catalytic substitutions of acetylenic hydrogen with bromoalkenes, iodoarenes and bromopyridines

Kenkichi Sonogashira, Yasuo Tohda, Nobue Hagihara · Tetrahedron Letters · 1975 · 5.1K citations

Chemical Engineering, Catalytic Substitutions, Engineering +8

Palladacycles as Structurally Defined Catalysts for the Heck Olefination of Chloro‐ and Bromoarenes

Wolfgang A. Herrmann, Karl Öfele, Claus‐Peter Reisinger et al. · Angewandte Chemie International Edition in English · 1995 · 815 citations

Halogenation, Type 1, Chemical Engineering +12

Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II): an effective catalyst for cross-coupling of secondary and primary alkyl Grignard and alkylzinc reagents with organic halides

Tamio Hayashi, Mitsuo Konishi, Yuji Kobori et al. · Journal of the American Chemical Society · 1984 · 747 citations

Chemical Engineering, Cross-coupling Reaction, Engineering +11

Regio- and stereoselective synthesis of γ-alkylidenebutenolides and related compounds

Ei‐ichi Negishi, Martin Kotora · Tetrahedron · 1997 · 242 citations

Organic Chemistry, Stereoselective Synthesis, Chemistry +2

Synthesis of halo enol lactones. Mechanism-based inactivators of serine proteases

Grant A. Krafft, John A. Katzenellenbogen · Journal of the American Chemical Society · 1981 · 194 citations

Halogenation, Bioorganic Chemistry, Engineering +13