Chemical Communications · 2011 · 102 citations · 23 references
Natural SciencesChemistryCatalysisInorganic ChemistrySpectroscopyCatalytic MechanismsReactive Oxygen SpeciesRedox CatalysisRedox ChemistryRedox ProcessesWater OxidationCatalyst MechanismsOxygen Evolution CatalystsPhotochemistry Of WaterReaction Intermediates SpectroscopyRuthenium-based Oxygen Evolution CatalystsStable IntermediatesWater Oxidation Intermediates
The Ru(V)==O species and other intermediates in O(2) evolution from water catalyzed by [Ru(terpy)(bpy)(OH(2))](2+) were spectrophotometrically characterized, and the spectral components observed were identified based on the TD-DFT calculations. Moreover, important insights into the rapid paths after the RDS were given by the DFT studies.
23
Javier J. Concepcion, Jonah W. Jurss, Joseph L. Templeton et al. · Journal of the American Chemical Society · 2008 · 666 citations