Journal of Applied Polymer Science · 2011 · 10 citations · 20 references
Natural SciencesChemistryMaterials SciencePolymer ChemistryPolymer EngineeringPolymer MaterialsFree-radical PolymerizationOptical PolymersPolymer StabilizationPolymerization ChemistryPolymerization KineticsThermoplastic PolymersLight-curing EfficiencyPhoto-initiator System EffectsPhotoinitiator ChemistryPhotopolymerizationPhotopolymerization KineticsThermal StabilityThermogravimetric CurvesThermogravimetric Data Analysis
Abstract 1‐Adamantyl acrylate was synthesized by reacting of 1‐adamantanol with acryloyl chloride in the presence of tertiary amine. The structure of monomer was characterized by FTIR and 1 H NMR spectroscopy. The influence of photoinitiator and monomer types on the photopolymerization kinetics of this monomer was investigated by real‐time infrared spectroscopy (RTIR). In the UV curing system, the introduction of 1‐adamantyl acrylate could significantly reduce the polymerization shrinkage. Thermogravimetric analysis of 1‐adamantyl acrylate indicated that 1‐adamantyl acrylate polymer has higher thermal stability than that of general commercial products. The results indicated that the synthesized monomer has good curing performance. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
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