Applied Physics Letters · 2012 · 33 citations · 16 references
Natural SciencesMaterials SciencePhysicsElectronic MaterialsSemiconductor DevicesSemiconductor MaterialsCarrier TransportSemiconductor DefectsSemiconductor PhysicsSolar Cell MaterialsSolar CellsThin Film Electrical PropertiesCharge Carrier DynamicsDisorder Effects In TransportDisorder-induced PropertiesDisordered SemiconductorsElectron DriftElectron MobilityPolycrystalline SemiconductorsPolycrystalline Thin Films
We report photocarrier time-of-flight measurements of electron drift mobilities for the p-type CuIn1−xGaxSe2 films incorporated in solar cells. The electron mobilities range from 0.02 to 0.05 cm2/Vs and are weakly temperature-dependent from 100–300 K. These values are lower than the range of electron Hall mobilities (2-1100 cm2/Vs) reported for n-type polycrystalline thin films and single crystals. We propose that the electron drift mobilities are properties of disorder-induced mobility edges and discuss how this disorder could increase cell efficiencies.
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