Journal of the American Chemical Society · 2000 · 101 citations · 12 references
Natural SciencesChemistryMaterials ScienceOptical MaterialsPolymer ChemistrySpectroscopyLight HarvestingLuminescent MaterialsNanostructured Energy MaterialsPhotochemical SynthesisPhotochemistryUltraviolet-visible SpectroscopyDendrimersDendritic Polymer StructureMild Reaction ConditionsOptical Properties
The first unsymmetrical conjugated dendrimer was synthesized using a rather simple approach that involves only one synthon and two sets of reaction conditions. This dendrimer shows broad absorption in the UV and visible range and possesses an intrinsic energy gradient from the outside branches to the core, naturally suggesting itself as a potentially efficient light harvesting material.
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A Convenient Synthesis of Ethynylarenes and Diethynylarenes
S. Takahashi, Y. Kuroyama, Kenkichi Sonogashira et al. · Synthesis · 1980 · 1.1K citations