Publication | Closed Access
Capture of Ni<sup>II</sup>, Cu<sup>I</sup>and Zn<sup>II</sup>by thiolate sulfurs of an N<sub>2</sub>S<sub>2</sub>Ni complex: A role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site
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Citations
21
References
2003
Year
Inorganic ChemistryMetallothiolate LigandBiochemistryThiolate SulfursNatural SciencesMetalloproteinCoordination ComplexBioorganometallic ChemistryMolecular ComplexChemistryObserved HeterogeneityChemical BiologySynthase Active SiteInorganic Compound
The metal binding affinity of an (N2S2)Ni bridging metallothiolate ligand (Zn2+ < Ni2+ < Cu+) gives precedent for the observed heterogeneity in ACS/CODH.
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