Die Makromolekulare Chemie · 1982 · 49 citations · 9 references
Phenolic CompoundsInorganic ChemistryChemical EngineeringRepetitive Reaction SequenceEngineeringC Nmr CharacteristicsPolymer ScienceX‐ray AnalysisOrganic ChemistryChemistryOligophenols 2–9Biomolecular EngineeringHeterocycle ChemistryPolymerization KineticsPolymer ReactionSynthetic ChemistryPolymer ChemistryPolymer Synthesis
Abstract The series of dinuclear to nonanuclear all‐ ortho methylene‐bridged oligophenols 2–9 has been synthesized according to a repetitive reaction sequence involving the C‐ ortho regiospecific condensation of appropriate phenoxymagnesium precursors with salicyl alcohol or paraformaldehyde. IR, UV, mass, 1 H and 13 C NMR characteristics of these oligomers are discussed. X‐ray crystal structures of 2, 3, and 4 are also reported.
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