Concepedia

Stepwise Insertion

Stepwise Insertion is a mechanistic pathway in organometallic chemistry whereby a ligand migrates sequentially to an adjacent coordinated unsaturated ligand within a metal complex, distinguished from concerted processes by its discrete, bond-forming steps involving intermediate species.

48

Publications

2.6K

Citations

202

Authors

74

Institutions

Publications per year

2017–2026

9

Parents

Publications

48

Rigid bidentate nitrogen ligands in organometallic chemistry and homogeneous catalysis. 3. Insertion of carbon monoxide and alkenes into palladium-carbon bonds of complexes containing rigid bidentate nitrogen ligands: the first example of isolated complexes in stepwise successive insertion reactions on the way to polyketones

Rob van Asselt, Esther E. C. G. Gielens, Richard E. Rülke et al. · Journal of the American Chemical Society · 1994 · 217 citations · Full text

, , +12

Size‐, Water‐, and Defect‐Regulated Potassium Manganese Hexacyanoferrate with Superior Cycling Stability and Rate Capability for Low‐Cost Sodium‐Ion Batteries

Aijun Zhou, Zemin Xu, Hongcai Gao et al. · Small · 2019 · 159 citations · Full text

, , +17

Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N–H Insertion

Shou‐Fei Zhu, Bin Xu, Guopeng Wang et al. · Journal of the American Chemical Society · 2011 · 140 citations

, , +17

Magnetic Properties Diagnostic for the Existence of Iron(II)-Iron(II) Bonds in Dinuclear Complexes Which Derive from Stepwise Insertion Reactions on Unsupported Iron-Aryl Bonds

Alain Klose, Euro Solari, Carlo Floriani et al. · Journal of the American Chemical Society · 1994 · 134 citations

, , +15

Stepwise Insertion and Inversion of a Type II Signal Anchor Sequence in the Ribosome-Sec61 Translocon Complex

Prasanna K. Devaraneni, Brian J. Conti, Yoshihiro Matsumura et al. · Cell · 2011 · 106 citations · Full text

, , +7

1–5 of 48

Authors

202

  1. AC
    Angiola Chiesi‐Villa

    University of Parma, Italy

    3 publications · 215 citations

    3

    h-index

  2. CF
    Carlo Floriani

    University of Lausanne, Switzerland

    3 publications · 215 citations

    3

    h-index

  3. CJ
    Cornelis J. Elsevier

    University of Amsterdam, Netherlands

    2 publications · 308 citations

    2

    h-index

  4. NR
    Nazzareno Re

    University of Chieti-Pescara, Italy

    2 publications · 199 citations

    2

    h-index

  5. ES
    Euro Solari

    University of Lausanne, Switzerland

    2 publications · 199 citations

    2

    h-index

1–5 of 202

Institutions

74

  1. Cardiff University

    Cardiff, United Kingdom

    2 h-index

    8 publications

    284 citations

  2. Centre National de la Recherche Scientifique

    Paris, France

    2 h-index

    4 publications

    118 citations

  3. Universität Hamburg

    Hamburg, Germany

    2 h-index

    6 publications

    255 citations

  4. University of Nebraska–Lincoln

    Lincoln, United States

    2 h-index

    5 publications

    425 citations

  5. University of Oxford

    Oxford, United Kingdom

    2 h-index

    6 publications

    213 citations

  6. Monash University

    Melbourne, Australia

    2 h-index

    4 publications

    142 citations

  7. Laboratoire de Chimie de Coordination

    Toulouse, France

    2 h-index

    4 publications

    118 citations

  8. Carnegie Mellon University

    Pittsburgh, United States

    1 h-index

    6 publications

    564 citations

1–8 of 74

Venues

  1. Journal of the American Chemical Society

    JACS · 7 publications · 749 citations

    7

    h-index

  2. Organometallics

    7 publications · 371 citations

    7

    h-index

  3. Chemische Berichte

    2 publications · 36 citations

    2

    h-index

  4. Chemical Communications

    ChemComm · 2 publications · 52 citations

    2

    h-index

  5. Organic Letters

    OL · 2 publications · 125 citations

    2

    h-index

1–5