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nanomaterials

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Seeded Shape-Control Nanomaterials

1988 - 2006

During this period, shape-directed synthesis emerged as the unifying paradigm for nanomaterials, leveraging seed-mediated growth, surfactant templates, and two-phase strategies to realize gold nanorods, nanoshapes, and anisotropic CdSe nanocrystals with controlled aspect ratios and facet exposure. Monodispersity and scalability became shared aims across metals, oxides, and semiconductors, achieved via size-selective avoidance, self-seeding, and controlled nucleation to yield iron-platinum nanoparticles, maghemite, silver nanowires, and CdSe nanocrystals. Shape- and composition-driven modulation of optical and electronic properties recurred across noble metals and CdSe nanostructures, linking plasmonic responses, exciton behavior, and photochemical reactivity to anisotropic morphologies. Carbon nanotube frameworks provided a complementary nanomaterial paradigm, illustrating intrinsic electronic structure and transport alongside colloidal nanoparticles.

Shape-directed synthesis emerges as a unifying paradigm, leveraging seed-mediated growth, surfactant templates, and two-phase strategies to realize gold nanorods, nanoshapes, and anisotropic CdSe nanocrystals with controlled aspect ratios and facet exposure [1], [10], [12], [14], [15], [16], [17].

Monodispersity and scalability become shared aims across metals, oxides, and semiconductors, achieved via size-selective avoidance, self-seeding, and controlled nucleation to yield FePt, maghemite, silver nanowires, and CdSe nanocrystals [2], [11], [13], [16], [19].

Shape- and composition-driven modulation of optical and electronic properties recurs across noble metals and CdSe nanostructures, linking plasmonic responses, exciton behavior, and photochemical reactivity to anisotropic morphologies [2], [4], [5], [8], [9], [10].

Carbon nanotube frameworks present a complementary nanomaterial paradigm, with crystalline ropes and SWCNTs illustrating intrinsic electronic structure and transport properties alongside colloidal nanoparticles [6], [20].

Surface-Engineered Two-Dimensional Nanosystems

2007 - 2013

Interfacial 2D MXene Engineering

2014 - 2024