Concepedia

Migratory Insertion Kinetics

Migratory Insertion Kinetics is a mechanistic framework in organometallic chemistry that describes the rate and pathway of the intramolecular migration of a ligand to an adjacent coordinated unsaturated substrate within a metal complex, distinguishing it from other elementary steps by its characterization of the kinetic and stereochemical features of the insertion process.

59

Publications

3.6K

Citations

192

Authors

60

Institutions

Publications per year

2017–2026

9

Parents

Publications

59

Low-Temperature Spectroscopic Observation of Chain Growth and Migratory Insertion Barriers in (α-Diimine)Ni(II) Olefin Polymerization Catalysts

Steven A. Svejda, Lynda K. Johnson, Maurice Brookhart · Journal of the American Chemical Society · 1999 · 302 citations

, , +16

Energetics of Migratory Insertion Reactions in Pd(II) Acyl Ethylene, Alkyl Ethylene, and Alkyl Carbonyl Complexes

Francis C. Rix, Maurice Brookhart · Journal of the American Chemical Society · 1995 · 196 citations

, , +14

Palladium(II) β-Agostic Alkyl Cations and Alkyl Ethylene Complexes:  Investigation of Polymer Chain Isomerization Mechanisms

Leigh Huff Shultz, Daniel J. Tempel, Maurice Brookhart · Journal of the American Chemical Society · 2001 · 187 citations

, , +16

Alpha- and beta-migratory insertion and elimination processes for alkyl complexes of permethyl-scandocene and permethyltantalocene

Gerard Parkin, Emilio E. Bunel, B. Burger et al. · Journal of Molecular Catalysis · 1987 · 159 citations

, , +11

Why is the Ir(III)-Mediated Amido Transfer Much Faster Than the Rh(III)-Mediated Reaction? A Combined Experimental and Computational Study

Yoonsu Park, Joon Heo, Mu‐Hyun Baik et al. · Journal of the American Chemical Society · 2016 · 159 citations

, , +16

1–5 of 59

Authors

192

  1. GJ
    Glenn J. Sunley

    BP (United Kingdom), United Kingdom

    5 publications · 292 citations

    5

    h-index

  2. MB
    Maurice Brookhart

    University of North Carolina at Chapel Hill, United States

    5 publications · 923 citations

    5

    h-index

  3. AH
    Anthony Haynes

    University of Sheffield, United Kingdom

    4 publications · 279 citations

    4

    h-index

  4. JF
    John F. Hartwig

    University of California, Berkeley, United States

    3 publications · 265 citations

    3

    h-index

  5. JE
    John E. Bercaw

    California Institute of Technology, United States

    3 publications · 268 citations

    3

    h-index

1–5 of 192

Institutions

60

  1. Centre National de la Recherche Scientifique

    Paris, France

    4 h-index

    14 publications

    551 citations

  2. University of North Carolina at Chapel Hill

    Chapel Hill, United States

    4 h-index

    12 publications

    2K citations

  3. University of Illinois Urbana-Champaign

    Urbana, United States

    3 h-index

    6 publications

    530 citations

  4. University of the Free State

    Bloemfontein, South Africa

    2 h-index

    9 publications

    265 citations

  5. Institut de Chimie Moléculaire et des Matériaux d'Orsay

    Orsay, France

    2 h-index

    10 publications

    470 citations

  6. University of Amsterdam

    Amsterdam, The Netherlands

    2 h-index

    9 publications

    402 citations

  7. University of Perugia

    Perugia, Italy

    2 h-index

    4 publications

    54 citations

  8. University of Chieti-Pescara

    Chieti, Italy

    2 h-index

    2 publications

    27 citations

1–8 of 60

Venues

  1. Journal of the American Chemical Society

    JACS · 20 publications · 2.3K citations

    19

    h-index

  2. Organometallics

    15 publications · 443 citations

    14

    h-index

  3. Inorganic Chemistry

    2 publications · 41 citations

    2

    h-index

  4. Chemistry - A European Journal

    2 publications · 172 citations

    2

    h-index

  5. 2

    h-index

1–5