Concepedia

Coordination-sphere Influence

Coordination-Sphere Influence is a mechanistic construct in organometallic chemistry that denotes the effect of ligands and spatial constraints within the metal's coordination sphere on the propensity and regioselectivity of β-hydride elimination, distinguishing it from analogous processes governed solely by electronic or substrate-specific factors.

365

Publications

18.6K

Citations

1.4K

Authors

441

Institutions

Publications per year

2017–2026

68

Parents

Publications

365

Controlled/“Living” Radical Polymerization. Kinetics of the Homogeneous Atom Transfer Radical Polymerization of Styrene

Krzysztof Matyjaszewski, Timothy E. Patten, Jianhui Xia · Journal of the American Chemical Society · 1997 · 882 citations

, , +17

Proton Relaxation in Dilute Solutions of Cobalt(II) and Nickel(II) Ions in Methanol and the Rate of Methanol Exchange of the Solvation Sphere

Z. Luz, S. Meiboom · The Journal of Chemical Physics · 1964 · 446 citations

, , +16

Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO<sub>2</sub> Reduction Catalyst

Timothy J. Schmeier, Graham E. Dobereiner, Robert H. Crabtree et al. · Journal of the American Chemical Society · 2011 · 434 citations

, , +16

The coordination chemistry of vanadium as related to its biological functions

Dieter Rehder · Coordination Chemistry Reviews · 1999 · 373 citations

, , +14

Coordination chemistry of vanadium in biological systems

Alison Butler, Carl J. Carrano · Coordination Chemistry Reviews · 1991 · 294 citations

, , +12

1–5 of 365

Authors

1.4K

  1. EC
    E.E. Castellano

    Universidade de São Paulo, Brazil

    5 publications · 100 citations

    5

    h-index

  2. SP
    Sam P. de Visser

    University of Manchester, United Kingdom

    5 publications · 303 citations

    5

    h-index

  3. RH
    Robert H. Crabtree

    Yale University, United States

    4 publications · 702 citations

    4

    h-index

  4. PA
    Peter A. Tasker

    University of Edinburgh, United Kingdom

    4 publications · 159 citations

    4

    h-index

  5. WJ
    Wendy J. Shaw

    Pacific Northwest National Laboratory, United States

    4 publications · 135 citations

    4

    h-index

1–5 of 1.4K

Institutions

441

  1. Centre National de la Recherche Scientifique

    Paris, France

    23 h-index

    122 publications

    8.9K citations

  2. University of Manchester

    Manchester, United Kingdom

    8 h-index

    22 publications

    1.3K citations

  3. Pacific Northwest National Laboratory

    Richland, United States

    7 h-index

    40 publications

    1.5K citations

  4. University of Illinois Urbana-Champaign

    Urbana, United States

    7 h-index

    27 publications

    1.1K citations

  5. Institut de Chimie

    Paris, France

    6 h-index

    22 publications

    1.6K citations

  6. Karlsruhe Institute of Technology

    Karlsruhe, Germany

    5 h-index

    10 publications

    637 citations

  7. Commissariat à l'Énergie Atomique et aux Énergies Alternatives

    Paris, France

    5 h-index

    16 publications

    982 citations

  8. Universidade de São Paulo

    São Paulo, Brazil

    5 h-index

    14 publications

    358 citations

1–8 of 441

Venues

  1. Inorganic Chemistry

    56 publications · 2.1K citations

    29

    h-index

  2. Journal of the American Chemical Society

    JACS · 31 publications · 3.7K citations

    25

    h-index

  3. Organometallics

    25 publications · 1.1K citations

    21

    h-index

  4. Chemistry - A European Journal

    17 publications · 1.2K citations

    15

    h-index

  5. Dalton Transactions

    16 publications · 601 citations

    14

    h-index

1–5