Concepedia

Alkyl Migratory Insertion

Alkyl Migratory Insertion is a fundamental organometallic reaction within the class of migratory insertion processes, distinguished by the migration of an alkyl group from a transition metal center to an adjacent coordinated unsaturated ligand, typically a carbonyl or olefin, resulting in the formation of a new carbon–carbon bond and a coordinated anionic ligand.

179

Publications

8.8K

Citations

596

Authors

174

Institutions

Publications per year

2017–2026

26

Parents

Publications

179

Gold-Catalyzed [4C+2C] Cycloadditions of Allenedienes, including an Enantioselective Version with New Phosphoramidite-Based Catalysts: Mechanistic Aspects of the Divergence between [4C+3C] and [4C+2C] Pathways

Isaac Alonso, Beatriz Trillo, Fernando López et al. · Journal of the American Chemical Society · 2009 · 274 citations

, , +15

Catalytic Enantioselective Cyclization/Cross-Coupling with Alkyl Electrophiles

Huan Cong, Gregory C. Fu · Journal of the American Chemical Society · 2014 · 207 citations · Full text

, , +15

Organozirconium Compounds in Organic Synthesis

Ei‐ichi Negishi, Tamotsu Takahashi · Synthesis · 1988 · 197 citations

, , +12

Energetics of Migratory Insertion Reactions in Pd(II) Acyl Ethylene, Alkyl Ethylene, and Alkyl Carbonyl Complexes

Francis C. Rix, Maurice Brookhart · Journal of the American Chemical Society · 1995 · 196 citations

, , +14

Palladium(II) β-Agostic Alkyl Cations and Alkyl Ethylene Complexes:  Investigation of Polymer Chain Isomerization Mechanisms

Leigh Huff Shultz, Daniel J. Tempel, Maurice Brookhart · Journal of the American Chemical Society · 2001 · 187 citations

, , +16

1–5 of 179

Authors

596

  1. MB
    Maurice Brookhart

    University of North Carolina at Chapel Hill, United States

    7 publications · 905 citations

    7

    h-index

  2. MG
    Michael G. Organ

    York University, Canada

    5 publications · 425 citations

    5

    h-index

  3. MP
    Matthew Pompeo

    York University, Canada

    4 publications · 366 citations

    4

    h-index

  4. SW
    Stefan Weber

    TU Wien, Austria

    4 publications · 149 citations

    4

    h-index

  5. LF
    Luı́s F. Veiros

    University of Lisbon, Portugal

    4 publications · 149 citations

    4

    h-index

1–5 of 596

Institutions

174

  1. Centre National de la Recherche Scientifique

    Paris, France

    12 h-index

    41 publications

    1.8K citations

  2. Chinese Academy of Sciences

    Beijing, China

    6 h-index

    14 publications

    995 citations

  3. York University

    Toronto, Canada

    5 h-index

    17 publications

    1.4K citations

  4. California Institute of Technology

    Pasadena, United States

    5 h-index

    17 publications

    1.7K citations

  5. Dow Chemical (United States)

    Midland, United States

    5 h-index

    10 publications

    822 citations

  6. Laboratoire de Chimie de Coordination

    Toulouse, France

    4 h-index

    10 publications

    477 citations

  7. University of Alberta

    Edmonton, Canada

    4 h-index

    16 publications

    403 citations

  8. Instituto de Investigaciones Químicas

    Seville, Spain

    4 h-index

    15 publications

    511 citations

1–8 of 174

Venues

  1. Journal of the American Chemical Society

    JACS · 40 publications · 3.2K citations

    33

    h-index

  2. Organometallics

    37 publications · 1.3K citations

    25

    h-index

  3. Angewandte Chemie International Edition

    13 publications · 1.2K citations

    13

    h-index

  4. Tetrahedron Letters

    11 publications · 261 citations

    11

    h-index

  5. Angewandte Chemie

    9 publications · 309 citations

    9

    h-index

1–5