A. Van Asselt

Alpha- and beta-migratory insertion and elimination processes for alkyl complexes of permethyl-scandocene and permethyltantalocene

Gerard Parkin, Emilio E. Bunel, B. Burger et al. · Journal of Molecular Catalysis · 1987 · 159 citations

Inorganic Chemistry, Alkyl Complexes, Elimination Processes +7

Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands?

Gerard Parkin, A. Van Asselt, David J. Leahy et al. · Inorganic Chemistry · 1992 · 134 citations

Inorganic Chemistry, Chemical Engineering, Engineering +9

Hydrido methylidene, hydrido vinylidene, hydrido oxo, and hydrido formaldehyde derivatives of bis(pentamethylcyclopentadienyl)tantalum

A. Van Asselt, Barbara J. Burger, V.C. Gibson et al. · Journal of the American Chemical Society · 1986 · 126 citations

Chemical Engineering, Derivative (Chemistry), Engineering +11

Dioxygen-derived peroxo-alkyl complexes of permethyltantalocene. Structural characterization of (.eta.5-C5Me5)2Ta(.eta.2-O2)(CH2C6H5) and acid-catalyzed rearrangement to oxo-alkoxide derivatives

A. Van Asselt, Mark S. Trimmer, L. M. Henling et al. · Journal of the American Chemical Society · 1988 · 63 citations

Inorganic Chemistry, Chemical Engineering, Structural Characterization +12

The tert-butyl peroxide complexes of permethylhafnocene, (.eta.5-C5Me5)2Hf(R)(OOCMe3). Stoichiometric transformation of alkyl tert-butyl peroxide derivatives to alkoxy tert-butoxides, (.eta.5-C5Me5)2Hf(OR)(OCMe3)

A. Van Asselt, Bernard D. Santarsiero, John E. Bercaw · Journal of the American Chemical Society · 1986 · 39 citations

Inorganic Chemistry, Engineering, Biochemistry +14