Carbon dioxide insertion into the iron-zirconium and ruthenium-zirconium bonds of the heterobimetallic complexes Cp(CO)2MZr(Cl)Cp2: direct production of the .mu.-.eta.1(C):.eta.2(O,O')-CO2 compounds Cp(CO)2MCO2Zr(Cl)Cp2

John R. Pinkes, Bryan D. Steffey, Jose C. Vites, +1

Organometallics

Materials ScienceInorganic ChemistryChemical EngineeringCarbon Dioxide InsertionRuthenium-zirconium Bonds +9

The making and breaking of carbon-hydrogen bonds on a metal cluster framework. Analysis of the tautomerization and deprotonation of Fe3(CO)9CH4 leading to the interconversion of FeHFe and CHFe interactions

Tamal Dutta, Jose C. Vites, Grant B. Jacobsen, +1

Organometallics

Materials ScienceInorganic ChemistryCluster ScienceMetal Cluster FrameworkChfe Interactions +13

The structure and properties of HFe3(CO)9BH3R and the conjugate bases [HFe3(CO)9BH2R]- (R = H and CH3). Inorganometallic analogs of hydrocarbyltriiron clusters

Jose C. Vites, Catherine E. Housecroft, Charles Eigenbrot, +3

Journal of the American Chemical Society

Cluster ScienceInorganic ChemistryChemical EngineeringEngineeringConjugate Bases +12

Cluster mimetics. The preparation and characterization of (.mu.-H)Fe3(CO)9(.mu.3-BH4)

Jose C. Vites, Charles Eigenbrot, Thomas P. Fehlner

Journal of the American Chemical Society

Materials ScienceInorganic ChemistryCluster ScienceEngineeringCluster Mimetics +11

Protons on a cluster surface. Reversible generation of agostic (carbon-hydrogen-metal) hydrogens from iron hydrides (iron-hydrogen-iron) on a saturated triiron cluster

Jose C. Vites, Geraldine Jacobsen, Tamal Dutta, +1

Journal of the American Chemical Society

Cluster ScienceChemical EngineeringEngineeringChemical AnalysisPhysics +11

Characterization of the heterobimetallic .mu.-(.eta.1-C:.eta.2-O,O') carbon dioxide complexes (.eta.5-C5H5)(CO)2MCO2M'(Cl)(.eta.5-C5H5)2 (M = iron, ruthenium; M' = titanium, zirconium)

Jose C. Vites, Bryan D. Steffey, Mary E. Giuseppetti-Dery, +1

Organometallics

Materials ScienceInorganic ChemistryChemical EngineeringInorganic CompoundEngineering +8

Cluster mimetics. 2. The preparation and characterization of (.mu.-H)(.mu.-CO)Fe3(CO)9BH2, (.mu.-CO)Fe3(CO)9BH2-, and Fe3(CO)9BH4-

Jose C. Vites, Catherine E. Housecroft, Grant B. Jacobsen, +1

Organometallics

Materials ScienceInorganic ChemistryCluster ScienceEngineeringCluster Mimetics +11

Reduction of the heterobimetallic .mu.-.eta.1(C):.eta.2(O,O')-CO2 complex Cp(CO)2Ru(CO2)Zr(Cl)Cp2 to its .mu.-.eta.1(C):.eta.1(O)-formaldehyde derivative Cp(CO)2Ru(CH2O)Zr(Cl)Cp2: hydride transfer occurs at ligated carbon monoxide

Bryan D. Steffey, Jose C. Vites, Alan R. Cutler

Organometallics

Inorganic ChemistryChemical EngineeringHydride TransferEngineeringBiochemistry +10

Reactions of (.mu.-H)3Fe3(CO)9(.mu.3-CCH3). Hydrogen displacement by CO and H2 elimination following deprotonation

Tamal Dutta, Xiangsheng Meng, Jose C. Vites, +1

Organometallics

Hydrogen DisplacementChemical EngineeringEngineeringChemical AnalysisReaction Process +13