J. Huhmann-Vincent

Highly Electrophilic [Re(CO)₄(PR₃)]⁺Center Binds Et₂O and CH₂Cl₂and Heterolytically Activates H₂

J. Huhmann-Vincent, Brian L. Scott, Gregory J. Kubas · Journal of the American Chemical Society · 1998 · 73 citations

Natural Sciences, Chemistry, Inorganic Chemistry +5

H2 binding to and silane alcoholysis on an electrophilic Mn(I) fragment with tied-back phosphite ligands. X-ray structure of a Mn–CH2Cl2 complex

Xinggao Fang, J. Huhmann-Vincent, Brian L. Scott et al. · Journal of Organometallic Chemistry · 2000 · 68 citations

Natural Sciences, Chemistry, Crystal Structure +14

Rhenium Complexes with Weakly Coordinating Solvent Ligands, <i>cis</i>-[Re(PR₃)(CO)₄(L)][BAr_F], L = CH₂Cl₂, Et₂O, NC₅F₅:  Decomposition to Chloride-Bridged Dimers in CH₂Cl₂ Solution

J. Huhmann-Vincent, Brian L. Scott, Gregory J. Kubas · Inorganic Chemistry · 1998 · 66 citations

Natural Sciences, Chemistry, Materials Science +16

Reactions of H2, silanes, and olefins with superelectrophilic cationic rhenium complexes: heterolytic cleavage of H2 and relation to the structure and function of hydrogenases

J. Huhmann-Vincent, Brian L. Scott, Gregory J. Kubas · Inorganica Chimica Acta · 1999 · 66 citations

Life Sciences, Biochemistry, Chemistry +10

Comparative Binding of H₂, N₂, and Related Ligands to [Mn(CO)₃(PCy₃)₂]⁺ and Other 16e Electrophiles. N₂ Does Not Coordinate, and H₂ Is the Most Versatile Weak Ligand

Andreas Toupadakis, Gregory J. Kubas, Wayne A. King et al. · Organometallics · 1998 · 64 citations

Natural Sciences, Chemistry, Green Chemistry +16