Andreas Toupadakis

Studies of the reactivity of binary thio- and tertiary oxothiomolybdates toward electrophiles. Reactions with dicarbomethoxyacetylene and the synthesis and structures of the [Et4N2[MoO(L)2], anti-[Et4N]2[Mo2O2S2(L)2]], syn-[Ph4P]2[Mo2O2S2(L)2].cntdot.2DMF, Ph4P]2[Mo(L)3]DMF.cntdot.C6H6, and [Ph4P]2[Mo2S2(L)4]2CH2Cl2 complexes (L = 1,2-dicarbomethoxy-1,2-ethylenedithiolate)

D. Coucouvanis, A. Hadjikyriacou, Andreas Toupadakis et al. · Inorganic Chemistry · 1991 · 93 citations

Natural Sciences, Chemistry, Inorganic Chemistry +11

Comparative Binding of H₂, N₂, and Related Ligands to [Mn(CO)₃(PCy₃)₂]⁺ and Other 16e Electrophiles. N₂ Does Not Coordinate, and H₂ Is the Most Versatile Weak Ligand

Andreas Toupadakis, Gregory J. Kubas, Wayne A. King et al. · Organometallics · 1998 · 64 citations

Natural Sciences, Chemistry, Green Chemistry +16

Synthesis of thiomolybdenyl complexes with [Mo2(S)2(O)2]2+ cores and substitutionally labile ligands. Crystal and molecular structure of the tris(dimethylformamide)dioxotetrasulfidodimolybdenum complex

D. Coucouvanis, Andreas Toupadakis, A. Hadjikyriacou · Inorganic Chemistry · 1988 · 41 citations

Natural Sciences, Biochemistry, Chemistry +14

An inorganic functional group approach to the systematic synthesis and reactivity studies of binuclear Mo/S and Mo/S/O complexes

D. Coucouvanis, Andreas Toupadakis, Sang‐Man Koo et al. · Polyhedron · 1989 · 35 citations

Natural Sciences, Chemistry, Inorganic Chemistry +15

Disproportionation of sulfur dioxide to octasulfur and sulfur trioxide on Cp*2Cr2S5. Crystallographic and sulfur-34-labeling evidence for an oxygen-transfer mechanism and observation of facile exchange of Cr2S5 core sulfurs with 34S. Structures of Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-.eta.1-SS.cntdot.SO2).cntdot.SO2 and Cp*2Cr2(.mu.-S)(.mu.-.eta.2-S2)(.mu.-SSO3)

Andreas Toupadakis, Gregory J. Kubas, Carol J. Burns · Inorganic Chemistry · 1992 · 17 citations

Natural Sciences, Chemistry, Materials Science +13