Emilie F. Gérard

What Drives Radical Halogenation versus Hydroxylation in Mononuclear Nonheme Iron Complexes? A Combined Experimental and Computational Study

Emilie F. Gérard, Vishal Yadav, David P. Goldberg et al. · Journal of the American Chemical Society · 2022 · 62 citations · Full text

Natural Sciences, Biochemistry, Chemistry +17

How Do Vanadium Chloroperoxidases Generate Hypochlorite from Hydrogen Peroxide and Chloride? A Computational Study

M. Qadri E. Mubarak, Emilie F. Gérard, Christopher F. Blanford et al. · ACS Catalysis · 2020 · 34 citations

Natural Sciences, Biochemistry, Chemistry +15

A non-canonical nucleophile unlocks a new mechanistic pathway in a designed enzyme

Amy E. Hutton, Jake Foster, Rebecca Crawshaw et al. · Nature Communications · 2024 · 34 citations · Full text

Engineering, Biochemistry, Molecular Biology +17

Proton-coupled electron transfer reactivities of electronically divergent heme superoxide intermediates: a kinetic, thermodynamic, and theoretical study

Pritam Mondal, Izumi Ishigami, Emilie F. Gérard et al. · Chemical Science · 2021 · 32 citations · Full text

Natural Sciences, Biochemistry, Chemistry +17

How Is Substrate Halogenation Triggered by the Vanadium Haloperoxidase from <i>Curvularia inaequalis</i>?

Emilie F. Gérard, Thirakorn Mokkawes, Linus O. Johannissen et al. · ACS Catalysis · 2023 · 29 citations · Full text

Pharmacy, Biochemistry, Biotechnology +17