A New Dirhodium(<scp>II</scp>) Carboxamidate Complex as a Chiral Lewis Acid Catalyst for Enantioselective Hetero‐Diels–Alder Reactions

Masahiro Anada, Takuya Washio, Naoyuki Shimada, +4

Angewandte Chemie International Edition

Chemical EngineeringEnantioselective SynthesisEngineeringCarboxamidate ComplexExcellent Enantioselectivities +13

Catalytic Enantioselective Amination of Silyl Enol Ethers Using Chiral Dirhodium(II) Carboxylates:  Asymmetric Formal Synthesis of (−)-Metazocine

Masahiro Anada, Masahiko Tanaka, Takuya Washio, +3

Organic Letters

Enantioselective amination of silylketene acetals with (N-arylsulfonylimino)phenyliodinanes catalyzed by chiral dirhodium(II) carboxylates: asymmetric synthesis of phenylglycine derivatives

Masahiko Tanaka, Yasunobu Kurosaki, Takuya Washio, +2

Tetrahedron Letters

Silylketene AcetalsDerivativesEngineeringChiral DirhodiumOrganic Chemistry +7

Asymmetric syntheses of diarylheptanoid natural products (−)-centrolobine and (−)-de-O-methylcentrolobine via hetero-Diels–Alder reaction catalyzed by dirhodium(II) tetrakis[(R)-3-(benzene-fused-phthalimido)-2-piperidinonate]

Takuya Washio, Reika Yamaguchi, Takumi Abe, +3

Tetrahedron

Asymmetric SynthesesEngineeringNatural SciencesDiversity-oriented SynthesisDiarylheptanoid Natural Products +9

Enantio- and diastereoselective hetero-Diels–Alder reactions between 2-aza-3-silyloxy-1,3-butadienes and aldehydes catalyzed by chiral dirhodium(ii) carboxamidates

Yudai Watanabe, Takuya Washio, J. Krishnamurthi, +2

Chemical Communications

Chemical EngineeringCross-coupling ReactionEngineeringHeterocyclicAlkene Metathesis +12

A New Dirhodium(<scp>II</scp>) Carboxamidate Complex as a Chiral Lewis Acid Catalyst for Enantioselective Hetero‐Diels–Alder Reactions

Masahiro Anada, Takuya Washio, Naoyuki Shimada, +4

Angewandte Chemie

Chemical EngineeringEnantioselective SynthesisEngineeringCarboxamidate ComplexBiochemistry +13

Highly enantioselective hetero-Diels–Alder reactions between Rawal’s diene and aldehydes catalyzed by chiral dirhodium(ii) carboxamidates

Yudai Watanabe, Takuya Washio, Naoyuki Shimada, +2

Chemical Communications

Catalytic asymmetric hetero-Diels–Alder route to a key intermediate for the synthesis of calyxin L

Takuya Washio, Hisanori Nambu, Masahiro Anada, +1

Tetrahedron Asymmetry

Key IntermediateEngineeringOrganic ChemistryCatalysisChemistry +5

A Short, Catalytic, Asymmetric Synthesis of Diospongins A and B by a One‐Pot, Sequential Hetero‐Diels–Alder/Mukaiyama–Michael Reaction Process

Masahiro Anada, Takuya Washio, Yudai Watanabe, +2

European Journal of Organic Chemistry

Diospongins ABioorganic ChemistryEngineeringOrganic ChemistryChemistry +14

Dirhodium(II) Tetrakis[N-benzene-fused Phthaloyl-(S)-piperidinonate] as a Chiral Lewis Acid: Catalytic Enantioselective Aldol Reactions of Acetate-derived Silylketene Acetals and Aldehydes

Shunichi Hashimoto, Takuya Washio, Seiichi Nakamura, +1

Heterocycles