Angewandte Chemie International Edition · 2004 · 120 citations · 37 references
Natural SciencesChemistryCatalysisInorganic ChemistryOrganic ChemistryCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MechanismsHeterocyclic ChemistryOrganic SynthesisAsymmetric Catalyst DesignChiral Catalyst DesignEnantioselective CatalysisEnantioselective Catalyst DesignEnantioselective SynthesisHetero Diels - Alder ReactionLewis Acid CatalysisPalladium Catalysts
Excellent enantioselectivities (up to 99 % ee) and turnover numbers (up to 48 000) were attained in the hetero-Diels–Alder reaction of a diverse range of aldehydes and activated dienes catalyzed by [Rh2(S-bptpi)4] (see scheme).
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Single enantiomers from a chiral-alcohol catalyst
Yong Huang, Aditya K. Unni, Avinash N. Thadani et al. · Nature · 2003 · 439 citations