Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO ₂

Ana Caballero, Emmanuelle Despagnet‐Ayoub, M. Mar Díaz‐Requejo, +8

Science

Chemical EngineeringEngineeringPerfluorinated Indazolylborate LigandsOrganic ChemistryOrganometallic Catalysis +8

Highly Regioselective Functionalization of Aliphatic Carbon−Hydrogen Bonds with a Perbromohomoscorpionate Copper(I) Catalyst

Ana Caballero, M. Mar Díaz‐Requejo, Tomás R. Belderraín, +3

Journal of the American Chemical Society

Room TemperatureChemical EngineeringCross-coupling ReactionEngineeringCarbene Source +10

Catalytic functionalization of low reactive C(sp³)–H and C(sp²)–H bonds of alkanes and arenes by carbene transfer from diazo compounds

Ana Caballero, M. Mar Díaz‐Requejo, Manuel R. Fructos, +3

Dalton Transactions

Ruthenium-Catalyzed Hydroboration and Dehydrogenative Borylation of Linear and Cyclic Alkenes with Pinacolborane

Ana Caballero, Sylviane Sabo‐Etienne

Organometallics

Chemical EngineeringRuthenium Complex Ruh2EngineeringAlkene MetathesisDehydrogenative Borylation +11

Copper(I)−Homoscorpionate Catalysts for the Preferential, Kinetically Controlled Cis Cyclopropanation of α-Olefins with Ethyl Diazoacetate

M. Mar Díaz‐Requejo, Ana Caballero, Tomás R. Belderraín, +3

Journal of the American Chemical Society

Chemical EngineeringVinyl AcetateEngineeringCarbene SourceAlkene Metathesis +8

Metal‐Catalyzed Olefin Cyclopropanation with Ethyl Diazoacetate: Control of the Diastereoselectivity

Ana Caballero, Auxiliadora Prieto, M. Mar Díaz‐Requejo, +1

European Journal of Inorganic Chemistry

Chemical EngineeringEngineeringAlkene MetathesisNatural SciencesCatalyst Design +11

Mechanism of Alkane C−H Bond Activation by Copper and Silver Homoscorpionate Complexes

Ataualpa Albert Carmo Braga, Feliu Maseras, Juan Urbano, +3

Organometallics

Transition StateInorganic ChemistryDft Becke3lyp CalculationsEngineeringBiochemistry +12

Functionalization of Carbon−Hydrogen Bonds of Hydrocarbons and Ethers via Carbene Insertion with Copper(I)−Homoscorpionate Catalysts

Ana Caballero, M. Mar Díaz‐Requejo, Tomás R. Belderraín, +3

Organometallics

Materials ScienceInorganic ChemistryChemical EngineeringEngineeringAlkene Metathesis +11

Discovering Copper for Methane C–H Bond Functionalization

Riccardo Gava, Andrea Olmos, Bárbara Noverges, +6

ACS Catalysis

Inorganic ChemistryChemical EngineeringEngineeringChemical BondOrganic Chemistry +9

A New Perfluorinated F₂₁-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F₂₁-Tp)M Catalysts (M = Cu, Ag)

Emmanuelle Despagnet‐Ayoub, Kane Jacob, Laure Vendier, +5

Organometallics

Materials ScienceInorganic ChemistryChemical EngineeringM CatalystsThalium Salt +13