Korean Journal of Food Science and Technology · 1982 · 11 citations · 0 references
PharmacyPharmaceutical AnalysisChemical KineticsThermal AnalysisThermodynamicsDecomposition AnalysisDegradation ProductsThermogravimetric AnalysisActivation EnergyFirst-order Degradation KineticsFirst-order KineticsPseudo-first-order KineticsRate ConstantsTemperature Effects On DegradationThermal Degradation ProductsThermal Degradation Studies
Kinetic study for the thermal degradation of ginsenosides in ginseng extract was conducted. The results indicate that the thermal degradation followed first order kinetics and rate constants varied substantially depending on the types of ginsenosides and heat treatment temperatures. Activation energy calculated by Arrhenius plots ranged from 16.80 kcal/mole to 30.10 kcal/mole and values ranged from 2.01 to 3.49. Correlation coefficients between the change of ginsenoside contents by thermal degradation and heat treatment temperature were . The dependence on temperatures of the decomposition rate constant of total ginsenoside can be expressed as exp(8898.8/T).