Deposition of Imidazole into Mesoporous Zirconium Metal–Organic Framework for Iodine Capture

Abstract

Efficient capture of radioiodine is essential for the protection of the ecological environment and the sustainable development of nuclear energy generation. Metal-organic frameworks (MOFs) and their derivatives provide alternative potential for overcoming the limitations of traditional iodine adsorbents. Herein this work, imidazole (Im) is dispersed into a robust mesoporous zirconium MOF <b>PCN-222</b> by the heat deposition method, forming a high-uniformity composite <b>Im@PCN-222</b>. The large pore size and marked chemical resistance skeleton of <b>PCN-222</b> allow the incorporation of Im to reach 43 wt % while surviving the chemical corrosion of activated Im. The nearly saturated loading of Im significantly benefits the sorption capability toward iodine and gives rise to an exceptional adsorption capacity of 10.04 g g^-1 and excellent recyclability. This value is higher than that of most of the MOFs and their derivatives. Further, Im was also successfully deposited onto the <b>PCN-222</b> functionalized porous Al₂O₃ ceramic filtration membrane, which endowed the hybrid membrane with efficient iodine sorption and separation properties. This work highlights a new strategy for the fabrication of the MOF-based radioiodine adsorption composite as well as MOF composite-based filters.