Concepedia

Unveiling new [1+1] Schiff-base macrocycles towards high energy-barrier hexagonal bipyramidal Dy(<scp>iii</scp>) single-molecule magnets

Alexandros S. Armenis, Arpan Mondal, S. R. Giblin, Catherine P. Raptopoulou, Vassilis Psycharis, Dimitris I. Alexandropoulos, Jinkui Tang, Richard A. Layfield, Theocharis C. Stamatatos

Chemical Communications · 2024 · 12 citations · 31 references

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Concepts

Abstract

Molecular engineering of the macrocycles’ donor atoms (LN6 vs LN3O3) has led to a mononuclear Dy III complex with hexagonal bipyramidal geometry and single-molecule magnet behavior with an effective energy barrier of 1300 K.

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