Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

Abstract

Single-molecule magnets (SMMs) containing only one metal center may represent the lower size limit for molecule-based magnetic information storage materials. Their current drawback is that all SMMs require liquid-helium cooling to show magnetic memory effects. We now report a chemical strategy to access the dysprosium metallocene cation [(Cp <i>ⁱ</i> ^Pr5)Dy(Cp*)]⁺ (Cp <i>ⁱ</i> ^Pr5, penta-iso-propylcyclopentadienyl; Cp<b>*,</b> pentamethylcyclopentadienyl), which displays magnetic hysteresis above liquid-nitrogen temperatures. An effective energy barrier to reversal of the magnetization of <i>U</i> _eff = 1541 wave number is also measured. The magnetic blocking temperature of <i>T</i> _B = 80 kelvin for this cation overcomes an essential barrier toward the development of nanomagnet devices that function at practical temperatures.