<i>Operando</i> Fe dissolution in Fe–N–C electrocatalysts during acidic oxygen reduction: impact of local pH change

Abstract

consumption and therefore pH increase (pH = 8-9) within the bulk Fe-N-C layer facilitate precipitation of Fe cations. This work provides a unified view on the Fe dissolution degradation mechanism for a model Fe-N-C in both high-throughput flow cell and practical operating GDE conditions, underscoring the crucial role of local pH in regulating the stability of the active sites.