Optimization of ultrathin polyamide nanofiltration membranes with sulfonated polyethersulfone interlayers for enhanced performance

Abstract

The “trade-off” effect of nanofiltration membranes may lead to problems of lower flux and higher energy cost, which limit their applications. In this work, an ultra-thin polyamide selective layer (34 nm in thickness, much lower than the conventional polyamide selective layer) was prepared by constructing a sulfonated polyethersulfone interlayer on the surface of polysulfone ultrafiltration membranes by liquid-phase deposition, taking advantage of the inhibitory effect of sulfonated polyethersulfone nanoparticles on the diffusion of piperazine. The prepared nanofiltration membrane exhibits a water flux per unit pressure of 33.2 L·m −2 ·h −1 ·bar −1 , which is more than 2.5 times higher than that of the nanofiltration membrane without the introduction of the interlayer (12.2 L·m −2 ·h −1 ·bar −1 ). Additionally, it has a high rejection of 98.8 % for Na 2 SO 4 , which surpasses the upper limit of the equilibrium of trade-off. The study also delves into the modulation mechanism of the interfacial polymerization process by the presence of a sulfonated polyethersulfone interlayer and explores the potential reasons for the water flux enhancement. This research will likely provide theoretical support and practical experience for further optimization of nanofiltration membrane performance.