Concepedia

<i>E</i>-Dakin reaction: oxidation of hydroxybenzaldehydes to phenols with electrochemically generated peroxodicarbonate as sustainable <i>ex-cell</i> oxidizer

Fiona Sprang, Niclas Schupp, Philipp J. Kohlpaintner, Lukas J. Gooßen, Siegfried R. Waldvogel

Green Chemistry · 2024 · 12 citations · 55 references

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Concepts

Abstract

Peroxodicarbonate, a sustainable electrochemically generated oxidizer, provides the means to transform abundant hydroxybenzaldehydes into valuable phenols in a safe and effective manner.

References

55

Metrics to ‘green’ chemistry—which are the best?

David J. C. Constable, Alan D. Curzons, Virginia Cunningham · Green Chemistry · 2002 · 887 citations

, , +15

Vanillin, a promising biobased building-block for monomer synthesis

Maxence Fache, Emilie Darroman, Vincent Besse et al. · Green Chemistry · 2014 · 480 citations

, , +9

The Selective Reaction of Aryl Halides with KOH:  Synthesis of Phenols, Aromatic Ethers, and Benzofurans

Kevin W. Anderson, Takashi Ikawa, Rachel E. Tundel et al. · Journal of the American Chemical Society · 2006 · 461 citations

, , +10

Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O<sub>2</sub> or Air

Yanghui Zhang, Jin‐Quan Yu · Journal of the American Chemical Society · 2009 · 423 citations

, , +7

Is electrosynthesis always green and advantageous compared to traditional methods?

Yong Yuan, Aiwen Lei · Nature Communications · 2020 · 397 citations · Full text

, , +13