Concepedia

A photo-driven traceless group directed electron–donor–acceptor (EDA) complex initiated radical coupling/dehydrogenation tandem reaction: access to 1-allyl/benzyl-3,4-dihydroisoquinoline

Tao Zhang, Xinxin Ren, Bin Wang, Weiwei Jin, Yu Xia, Shaofeng Wu, Chenjiang Liu, Yonghong Zhang

Organic Chemistry Frontiers · 2024 · 19 citations · 34 references

DOI

Concepts

Abstract

A metal-free and mild one pot protocol for the traceless group directed and electron–donor–acceptor (EDA) complex initiated radical coupling/dehydrogenation of arylazo-protected tetrahydroisoquinolines with benzyl/allyl bromide is reported.

References

34

Organic Synthesis Enabled by Light-Irradiation of EDA Complexes: Theoretical Background and Synthetic Applications

Carolina G. S. Lima, Thiago M. Lima, M.T. Duarte et al. · ACS Catalysis · 2016 · 727 citations

, , +16

A Molecular Iron Catalyst for the Acceptorless Dehydrogenation and Hydrogenation of N-Heterocycles

Sumit Chakraborty, William W. Brennessel, William D. Jones · Journal of the American Chemical Society · 2014 · 480 citations

, , +16

Fresh Look at Electron-Transfer Mechanisms via the Donor/Acceptor Bindings in the Critical Encounter Complex

Sergiy V. Rosokha, Jay K. Kochi · Accounts of Chemical Research · 2008 · 459 citations

, , +17

Visible‐Light‐Driven Palladium‐Catalyzed Radical Alkylation of C−H Bonds with Unactivated Alkyl Bromides

Wen‐Jun Zhou, Guangmei Cao, Shen Guo et al. · Angewandte Chemie International Edition · 2017 · 245 citations

, , +16

Control of Charge Transfer in Donor/Acceptor Metal–Organic Frameworks

Hitoshi Miyasaka · Accounts of Chemical Research · 2012 · 243 citations

, , +17