Green Chemistry · 2023 · 46 citations · 55 references
Natural SciencesMaterials EngineeringMaterials ScienceElectrochemistryInterface ScienceMaterials ChemistryCharge Transfer ReactionsElectrochemical SynthesisElectrode KineticsElectrode MaterialsElectrode-electrolyte InterfacesCovalent Organic FrameworksElectrocatalyst DesignElectron TransferHeterostructure MaterialsHybrid Electrochemical MaterialsMetal-organic Framework CatalystsMetal-organic FrameworksSelectivity
The in situ fabrication of imine-bonded porphyrin COFs and an MXene heterostructure can accelerate the electron transfer at interfaces, exhibiting superior electrocatalytic CO 2 reduction selectivity with 97.28% TOF value (CO 2 -to-CO) at a bias of −0.6 V vs. RHE.
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