1c:I[419806,["/_next/static/chunks/bb923814e1f4d2e9.js","/_next/static/chunks/dd3ee9f5b7716ca6.js","/_next/static/chunks/4204a0ae82542ca8.js","/_next/static/chunks/1270dead247da766.js","/_next/static/chunks/6e1aa89a642f40be.js","/_next/static/chunks/2d7aa753e81324a8.js","/_next/static/chunks/8ffd0b71567920d8.js","/_next/static/chunks/67ea6dfd21f16c5f.js","/_next/static/chunks/24eb4379f68013fd.js","/_next/static/chunks/b8cd775ffdf935bd.js","/_next/static/chunks/983103cd9eb7b428.js","/_next/static/chunks/263f2cdcb9aa2341.js","/_next/static/chunks/294b9525248c8e5f.js"],"default"] 1d:T428,Isolated single atomic site catalysts have attracted great interest due to their remarkable catalytic properties. Because of their high surface energy, single atoms are highly mobile and tend to form aggregate during synthetic and catalytic processes. Therefore, it is a significant challenge to fabricate isolated single atomic site catalysts with good stability. Herein, a gentle method to stabilize single atomic site metal by constructing defects on the surface of supports is presented. As a proof of concept, single atomic site Au supported on defective TiO₂ nanosheets is prepared and it is discovered that (1) the surface defects on TiO₂ nanosheets can effectively stabilize Au single atomic sites through forming the Ti-Au-Ti structure; and (2) the Ti-Au-Ti structure can also promote the catalytic properties through reducing the energy barrier and relieving the competitive adsorption on isolated Au atomic sites. It is believed that this work paves a way to design stable and active single atomic site catalysts on oxide supports.1e:T520,The catalytic activity of metal clusters is closely related with the support; however, knowledge on the influence of the support on the catalytic activity is scarce. We demonstrate that Pt nanoclusters (NCs) anchored on porous TiO₂ nanosheets with rich oxygen vacancies (V_O -rich Pt/TiO₂ ) and deficient oxygen vacancies (V_O -deficient Pt/TiO₂ ), display significantly different catalytic activity for the hydrogen evolution reaction (HER), in which V_O -rich Pt/TiO₂ shows a mass activity of 45.28 A mg_Pt ^-1 at -0.1 V vs. RHE, which is 16.7 and 58.8 times higher than those of V_O -deficient Pt/TiO₂ and commercial Pt/C, respectively. DFT calculations and in situ Raman spectra suggest that porous TiO₂ with rich oxygen vacancies can simultaneously achieve reversed charge transfer (electrons transfer from TiO₂ to Pt NCs) and enhanced hydrogen spillover from Pt NCs to the TiO₂ support, which leads to electron-rich Pt NCs being amenable to proton reduction of absorbed H*, as well as the acceleration of hydrogen desorption at Pt catalytic sites-both promoting the HER. Our work provides a new strategy for rational design of highly efficient HER catalysts.

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