Room-temperature wavelike exciton transport in a van der Waals superatomic semiconductor

Abstract

The transport of energy and information in semiconductors is limited by scattering between electronic carriers and lattice phonons, resulting in diffusive and lossy transport that curtails all semiconductor technologies. Using Re 6 Se 8 Cl 2 , a van der Waals (vdW) superatomic semiconductor, we demonstrate the formation of acoustic exciton-polarons, an electronic quasiparticle shielded from phonon scattering. We directly imaged polaron transport in Re 6 Se 8 Cl 2 at room temperature, revealing quasi-ballistic, wavelike propagation sustained for a nanosecond and several micrometers. Shielded polaron transport leads to electronic energy propagation lengths orders of magnitude greater than in other vdW semiconductors, exceeding even silicon over a nanosecond. We propose that, counterintuitively, quasi-flat electronic bands and strong exciton–acoustic phonon coupling are together responsible for the transport properties of Re 6 Se 8 Cl 2 , establishing a path to ballistic room-temperature semiconductors.