Concepedia

Total synthesis of atropisomeric indolosesquiterpenoids <i>via</i> N–N bond formation: dixiamycins A and B

Rhituparna Nandi, Sovan Niyogi, Sourav Kundu, Vipin R. Gavit, Mintu Munda, Ranjit Murmu, Alakesh Bisai

Chemical Science · 2023 · 21 citations · 32 references

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Abstract

The total synthesis of the naturally occurring N–N atropo-diastereomers dixiamycin A (1a) and dixiamycin B (1b) using a key Cu( i )-catalyzed aerobic oxidation of xiamycin A methyl ester (2b) was developed.

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