Concepedia

Negative solvatochromism and sign inversion of circularly polarized luminescence in chiral exciplexes as a function of solvent polarity

Patthira Sumsalee, Pierpaolo Morgante, Grégory Pieters, Jeanne Crassous, Jochen Autschbach, Ludovic Favereau

Journal of Materials Chemistry C · 2023 · 35 citations · 46 references

DOIFull text

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Concepts

Abstract

The properties of chiral donor–acceptor systems displaying CPL sign inversion are investigated in solvents of different polarity. The solvent enables control of their deexcitation pathways favoring either locally excited or charge-transfer states.

References

46

Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy

Florian Weigend, Reinhart Ahlrichs · Physical Chemistry Chemical Physics · 2005 · 29.9K citations

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Energies, structures, and electronic properties of molecules in solution with the C‐PCM solvation model

Maurizio Cossi, Nadia Rega, Giovanni Scalmani et al. · Journal of Computational Chemistry · 2003 · 7.9K citations

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Recent Progress on Circularly Polarized Luminescent Materials for Organic Optoelectronic Devices

Jianmei Han, Song Guo, Hu Jie Lu et al. · Advanced Optical Materials · 2018 · 731 citations

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Circularly Polarized Luminescence and Circular Dichroisms in Small Organic Molecules: Correlation between Excitation and Emission Dissymmetry Factors

Hiroki Tanaka, Yoshihisa Inoue, Tadashi Mori · ChemPhotoChem · 2018 · 717 citations

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Effective method for the computation of optical spectra of large molecules at finite temperature including the Duschinsky and Herzberg–Teller effect: The Qx band of porphyrin as a case study

Fabrizio Santoro, Alessandro Lami, Roberto Improta et al. · The Journal of Chemical Physics · 2008 · 680 citations

, , +17