ACS Omega · 2023 · 66 citations · 57 references
Natural SciencesMaterials EngineeringMaterials ScienceCeramic MaterialsCeramicsElectronic MaterialsCeramic TechnologyDielectric CeramicsElectrical Properties Of CeramicsPorous CeramicsThermal Properties Of CeramicsThermoelectric MaterialsBand GapBarium TitanateCeramic CapacitorsElectrical PropertiesMultilayer Ceramic CapacitorsSol-gel MaterialsSol-gel ProcessingThermal Conductivity
High Resolution Image Download MS PowerPoint Slide The use of electronic devices that incorporate multilayer ceramic capacitors (MLCCs) is on the rise, requiring materials with good electrical properties and a narrow band gap. This study synthesized yttrium-substituted barium titanate (Ba 1– x Y x TiO 3, BYT) using a sol–gel process at 950 °C with varying concentrations of yttrium (0 ≤ x ≤ 0.3). X-ray diffraction analysis showed that the tetragonal phase became less pronounced as the yttrium content increased. The samples had varying grain sizes and porosity, with the BY30%T sample having the narrowest band gap at 2.21 eV. The BYT ceramic with 30% yttrium had a thermal conductivity of up to 7 W/m K and an electrical conductivity down to 0.002 (Ω cm) −1 at 180 °C. The current–voltage characteristics of the BYT MLCC were also studied, showing potential use in next-generation high-capacity MLCCs. This work presents BYT as a promising material for these types of capacitors.
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