Preparation of Heterojunctions Based on Cs3Bi2Br9 Nanocrystals and g-C3N4 Nanosheets for Photocatalytic Hydrogen Evolution

María Medina‐Llamas, Andrea Speltini, Antonella Profumo, Francesca Panzarea, Antonella Milella, Francesco Fracassi, Andrea Listorti, Lorenzo Malavasi

Nanomaterials · 2023 · 27 citations · 31 references

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Abstract

Heterojunctions based on metal halide perovskites (MHPs) are promising systems for the photocatalytic hydrogen evolution reaction (HER). In this work, we coupled Cs<sub>3</sub>Bi<sub>2</sub>Br<sub>9</sub> nanocrystals (NCs), obtained by wet ball milling synthesis, with g-C<sub>3</sub>N<sub>4</sub> nanosheets (NSs), produced by thermal oxidation of bulk g-C<sub>3</sub>N<sub>4,</sub> in air. These methods are reproducible, inexpensive and easy to scale up. Heterojunctions with different loadings of Cs<sub>3</sub>Bi<sub>2</sub>Br<sub>9</sub> NCs were fully characterised and tested for the HER. A relevant improvement of H<sub>2</sub> production with respect to pristine carbon nitride was achieved at low NCs levels reaching values up to about 4600 µmol g<sup>-1</sup> h<sup>-1</sup>. This work aims to provide insights into the synthesis of inexpensive and high-performing heterojunctions using MHP for photocatalytic applications.

References

31