Concepedia

Synthesis and <sup>83</sup>Kr NMR spectroscopy of Kr@C<sub>60</sub>

Gabriela Hoffman, George R. Bacanu, Elizabeth S. Marsden, Mark C. Walkey, Mohamed Sabba, Sally Bloodworth, Graham J. Tizzard, Malcolm H. Levitt, Richard J. Whitby

Chemical Communications · 2022 · 19 citations · 40 references

DOIFull text

Open access

Concepts

Abstract

Synthesis of Kr@C 60 is achieved by a synthetic route that involves quantitative encapsulation of krypton by an open-cage derivative of C 60 . Fine structure is observed in the 13 C NMR spectrum, and 83 Kr NMR characterisation is carried out.

References

40

Encapsulation of Molecular Hydrogen in Fullerene C <sub>60</sub> by Organic Synthesis

Kôichi Komatsu, Michihisa Murata, Yasujiro Murata · Science · 2005 · 634 citations

, , +13

Further conventions for NMR shielding and chemical shifts (IUPAC Recommendations 2008)

Robin K. Harris, Edwin D. Becker, Sônia Maria Cabral de Menezes et al. · Pure and Applied Chemistry · 2008 · 623 citations · Full text

, , +10

A Single Molecule of Water Encapsulated in Fullerene C <sub>60</sub>

Kei Kurotobi, Yasujiro Murata · Science · 2011 · 526 citations

, , +17

Noble Gas Atoms Inside Fullerenes

Martin Saunders, R. J. Cross, Hugo A. Jiménez‐Vázquez et al. · Science · 1996 · 472 citations

, , +11

Probing the interior of fullerenes by 3He NMR spectroscopy of endohedral 3He@C60 and 3He@C70

Martin Saunders, Hugo A. Jiménez‐Vázquez, R. J. Cross et al. · Nature · 1994 · 348 citations

, , +10