npj Materials Degradation · 2022 · 17 citations · 55 references
Natural SciencesMaterials EngineeringMaterials ScienceCorrosion ScienceMetallic MaterialsMetallurgyAlloysCorrosion EngineeringCorrosion KineticsCorrosion MechanismsCorrosion-resistant MaterialsElectrochemical CorrosionCatalytic ActivityElectrochemical Corrosion KineticsElectrochemical MechanismsHydrogen EvolutionHydrogen Evolution ReactionHydrogen Evolution Reaction KineticsMagnesium AlloysPotentiodynamic Polarization
Abstract The corrosion performance of binder jet additive samples is compared with cast samples through potentiodynamic polarization in Na 2 SO 4 solution. Higher zinc levels in the magnesium matrix and the presence of MgO within the microstructure of the binder jet printed alloy contribute to increases in the anodic and cathodic kinetics, respectively. It is proposed that electron inhomogeneity at the Mg/MgO interface in the binder jet printed alloy is the source of the catalytic activity of the hydrogen evolution reaction. The removal of MgO inclusions suppressed the cathodic reaction relative to the large increase in kinetics seen in similarly treated cast samples.
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Corrosion of magnesium alloys: the role of alloying
Kateryna Gusieva, C.H.J. Davies, John R. Scully et al. · International Materials Reviews · 2014 · 524 citations · Full text
Natural Sciences, Materials Engineering, Materials Science +17