Concepedia

Catalytic Lewis Base Additive Enables Selective Copper-Catalyzed Borylative α-C–H Allylation of Alicyclic Amines

Borja Pérez-Saavedra, Álvaro Velasco‐Rubio, Eva Rivera‐Chao, Jesús A. Varela, Carlos Saá, Martín Fañanás‐Mastral

Journal of the American Chemical Society · 2022 · 16 citations · 53 references

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Abstract

-benzoyl hydroxylamine, thus enabling in situ transformation of the latter into an alicyclic imine which undergoes selective C-C bond formation with the allylcopper species.

References

53

COPASI—a COmplex PAthway SImulator

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New aryl/heteroaryl CN bond cross-coupling reactions via arylboronic acid/cupric acetate arylation

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Discovery of an α-Amino C–H Arylation Reaction Using the Strategy of Accelerated Serendipity

Andrew McNally, Christopher K. Prier, David W. C. MacMillan · Science · 2011 · 1K citations

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Amine Functionalization via Oxidative Photoredox Catalysis: Methodology Development and Complex Molecule Synthesis

Joel W. Beatty, Corey R. J. Stephenson · Accounts of Chemical Research · 2015 · 725 citations · Full text

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Native functionality in triple catalytic cross-coupling: sp <sup>3</sup> C–H bonds as latent nucleophiles

Megan H. Shaw, Valerie W. Shurtleff, Jack A. Terrett et al. · Science · 2016 · 630 citations · Full text

, , +17