Concepedia

Abnormal NHC ruthenium catalysts: mechanistic investigations of their preparation and steric influence on catalytic performance

Alexander D. Böth, Michael J. Sauer, Walter Baratta, Fritz E. Kühn

Catalysis Science & Technology · 2022 · 10 citations · 41 references

DOI

Concepts

Abstract

Preparation of bis-aNHC Ru catalysts, identification of formation intermediates and application in transfer hydrogenation and Oppenauer-type oxidation, observing an inversion in activity appearing to be dependent on steric hindrance.

References

41

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1,2,3-Triazolylidenes as Versatile Abnormal Carbene Ligands for Late Transition Metals

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